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Mesoporous silicon sulfonic acid as a highly efficient and stable catalyst for the selective hydroamination

Jingbin Wen, Kuiyi You, Minjuan Chen, Jian Jian, Fangfang Zhao, Pingle Liu, Qiuhong Ai, He’an Luo

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 3,   Pages 654-665 doi: 10.1007/s11705-020-1973-2

Abstract: In this work, a new mesoporous silicon sulfonic acid catalyst derived from silicic acid has been successfullyThe physicochemical properties of mesoporous silicon sulfonic acid catalysts have been systematicallyThe mesoporous silicon sulfonic acid exhibits excellent catalytic performance and stability in the vaporThe developed mesoporous silicon sulfonic acid catalyst shows advantages of low cost, superior acid siteMoreover, a possible catalytic hydroamination reaction mechanism over silicon sulfonic acid was suggested

Keywords： mesoporous silicon sulfonic acid     catalytic hydroamination     cyclohexene     dicyclohexylamine     vapor phase    

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Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 8,   Pages 1198-1210 doi: 10.1007/s11705-021-2133-z

Abstract: Sulfonic acid functionalized mesoporous silica based solid acid catalysts with different morphology wereThe sulfonic acid functionalized mesoporous silica catalysts of spherical shape and the cube shape werecatalytic biodiesel production reaction over the catalysts were studied by esterification of free fatty acid, oleic acid with methanol.It was sulfonated cubic shape mesoporous silica which exhibited better activity as compared to the spherical

Keywords： solid acid catalyst     mesoporous silica     sulfonic acid     biodiesel     esterification     oleic acid    

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Enhancing the photoelectrochemical performance of p-silicon through TiO coating decorated with mesoporous

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 772-780 doi: 10.1007/s11708-021-0783-7

Abstract: In this paper, a highly-ordered mesoporous MoS2 was synthesized and decorated onto a TiO2 protected p-silicon substrate.

Keywords： photoelectrocatalysis     hydrogen evolution     Si photocathode     mesoporous MoS2    

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Erratum to: Enhancing the photoelectrochemical performance of p-silicon through TiO coating decoratedwith mesoporous MoS

Frontiers in Energy 2022, Volume 16, Issue 5,   Pages 876-877 doi: 10.1007/s11708-022-0832-x

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One-pot three-component Mannich reaction catalyzed by sucrose char sulfonic acid

Qiong XU, Zhigao YANG, Dulin YIN, Jihui WANG

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 2,   Pages 201-205 doi: 10.1007/s11705-009-0052-5

Abstract: Sucrose char sulfonic acid efficiently catalyzed the one-pot three-component Mannich reaction of ketones

Keywords： One–pot synthesis     b-amino ketone     char sulfonic acid     2-acetylpyrazine     catalysis    

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Enhanced Fenton-like process over Cu/L(+)-ascorbic acid co-doping mesoporous silica for toxicity reduction

Frontiers of Environmental Science & Engineering 2023, Volume 18, Issue 4, doi: 10.1007/s11783-024-1804-7

Abstract:

● Cu-C-MSNs are developed via a co-doping step of Cu with L(+)-ascorbic acid

Keywords： Cation-π structures     Polarization electric field     Fenton-like process     Contaminants cleavage    

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Ti incorporation in MCM-41 mesoporous molecular sieves using hydrothermal synthesis

Shengping WANG, Changqing MA, Yun SHI, Xinbin MA

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 1,   Pages 95-103 doi: 10.1007/s11705-014-1405-2

Abstract: Titanium-containing mesoporous materials (Ti-MCM-41) were obtained by hydrothermal synthesis.It was concluded that the Ti is incorporated into the framework of the MCM-41 and formed weak Lewis acidA large number of Ti(IV) sites coupled with the mesoporous structure and large pore diameters are favorable

Keywords： Ti-MCM-41     mesoporous molecular sieve     acid sites     transesterification     hydrothermal synthesis    

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Magnetic KIT-6 nano-composite and its amino derivatives as convenient adsorbent for U(VI) sequestration

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 2037-2049 doi: 10.1007/s11705-023-2358-0

Abstract: Although mesoporous silica with magnetically hybridized two-dimensional channel structures has been wellHerein, we successfully prepared magnetic KIT-6 nano-composite and its amino derivatives by bearing acid-resistantendothermic nature and ionic strength independence, and the adsorbents can be easily regenerated by acidfindings of this work further demonstrate the potential broad application prospects of magnetic hybrid mesoporous

Keywords： magnetic nanoparticle     3D mesoporous silica     amino functionalization     adsorption of U(VI)     acid resistance    

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Review on research and application of mesoporous transitional metal oxides in water treatment

Minghao SUI, Lei SHE

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 6,   Pages 795-802 doi: 10.1007/s11783-013-0521-4

Abstract: This paper reviews the application of mesoporous transitional metal oxides in water treatment on basisMesoporous transitional metal oxides are characterized by their intrinsic features, such as a high surface

Keywords： mesoporous materials     transitional metal oxides     catalysis     adsorption     water treatment    

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Effects of nano-silicon and common silicon on lead uptake and translocation in two rice cultivars

Jianguo LIU,Hui CAI,Congcong MEI,Mingxin WANG

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 5,   Pages 905-911 doi: 10.1007/s11783-015-0786-x

Abstract: The current study investigated the effects of nano-silicon (Si) and common Si on lead (Pb) toxicity,

Keywords： silicon (Si)     lead (Pb)     rice (Oryza sativa L.)     toxicity     accumulation    

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Enhanced activation of persulfate using mesoporous silica spheres augmented Cu–Al bimetallic oxide particles

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1581-1592 doi: 10.1007/s11705-023-2327-7

Abstract: Herein, Cu–Al bimetallic oxide was synthesized and mixed with mesoporous silica spheres via a simpledispersion spectroscopy, Cu–Al bimetallic oxide was determined as CuO-Al2O3, and mesoporousFurthermore, mesoporous silica spheres augment not only enhanced bisphenol A adsorption but also alleviated

Keywords： Cu–Al bimetallic oxides     mesoporous silica spheres     peroxydisulfate     bisphenol A    

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Synthesis of ordered cerium-doped cubic mesoporous silica using long-chain ionic liquid as template

YUE Hongxia, ZHAO Hongmei, LIU Longjiang, WANG Siping, Ruan Qiong, WANG Tongwen

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 2,   Pages 135-139 doi: 10.1007/s11705-008-0031-2

Abstract: This mesoporous material exhibits a pore architecture which is cubic 3 gyroid and possesses a large surface

Keywords： mesoporous     CmimCl/Si     tendency     mesostructure     synthesis procedure    

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Computer modeling of crystal growth of silicon for solar cells

Lijun LIU, Xin LIU, Zaoyang LI, Koichi KAKIMOTO

Frontiers in Energy 2011, Volume 5, Issue 3,   Pages 305-312 doi: 10.1007/s11708-011-0155-9

Abstract: A computer simulator with a global model of heat transfer during crystal growth of Si for solar cells is developed. The convective, conductive, and radiative heat transfers in the furnace are solved together in a coupled manner using the finite volume method. A three-dimensional (3D) global heat transfer model with 3D features is especially made suitable for any crystal growth, while the requirement for computer resources is kept permissible for engineering applications. A structured/unstructured combined mesh scheme is proposed to improve the efficiency and accuracy of the simulation. A dynamic model for the melt-crystal (mc) interface is developed to predict the phase interface behavior in a crystal growth process. Dynamic models for impurities and precipitates are also incorporated into the simulator. Applications of the computer simulator to Czochralski (CZ) growth processes and directional solidification processes of Si crystals for solar cells are introduced. Some typical results, including the turbulent melt flow in a large-scale crucible of a CZ-Si process, the dynamic behaviors of the mc interface, and the transport and distributions of impurities and precipitates, such as oxygen, carbon, and SiC particles, are presented and discussed. The findings show the importance of computer modeling as an effective tool in the analysis and improvement of crystal growth processes and furnace designs for solar Si material.

Keywords： computer modeling     silicon     crystal growth     solar cells    

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The modification of titanium in mesoporous silica for Co-based Fischer–Tropsch catalysts

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 8,   Pages 1224-1236 doi: 10.1007/s11705-022-2139-1

Abstract: Ordered SBA-15 mesoporous silica with incorporated titanium was successfully synthesized via a one-potThe results showed that titanium was successfully incorporated into the mesoporous silica framework witha limited amount of titanium (Si/Ti > 20), and the mesoporous structure was retained.

Keywords： Fischer–Tropsch synthesis     titanium incorporation     mesoporous silica     metal-support interactions     C   

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Copper nanoparticles/polyaniline-derived mesoporous carbon electrocatalysts for hydrazine oxidation

Tao Zhang, Tewodros Asefa

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 329-338 doi: 10.1007/s11705-018-1741-8

Abstract:

Copper nanoparticles-decorated polyaniline-derived mesoporous carbon that can serve as noble metal-free

Keywords： copper nanoparticles     mesoporous carbon     noble metal-free electrocatalyst     hydrazine oxidation reaction    

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Title Author Date Type Operation

Mesoporous silicon sulfonic acid as a highly efficient and stable catalyst for the selective hydroamination

Jingbin Wen, Kuiyi You, Minjuan Chen, Jian Jian, Fangfang Zhao, Pingle Liu, Qiuhong Ai, He’an Luo

Journal Article

Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production

Journal Article

Enhancing the photoelectrochemical performance of p-silicon through TiO coating decorated with mesoporous

Journal Article

Erratum to: Enhancing the photoelectrochemical performance of p-silicon through TiO coating decoratedwith mesoporous MoS

Journal Article

One-pot three-component Mannich reaction catalyzed by sucrose char sulfonic acid

Qiong XU, Zhigao YANG, Dulin YIN, Jihui WANG

Journal Article

Enhanced Fenton-like process over Cu/L(+)-ascorbic acid co-doping mesoporous silica for toxicity reduction

Journal Article

Ti incorporation in MCM-41 mesoporous molecular sieves using hydrothermal synthesis

Shengping WANG, Changqing MA, Yun SHI, Xinbin MA

Journal Article

Magnetic KIT-6 nano-composite and its amino derivatives as convenient adsorbent for U(VI) sequestration

Journal Article

Review on research and application of mesoporous transitional metal oxides in water treatment

Minghao SUI, Lei SHE

Journal Article

Effects of nano-silicon and common silicon on lead uptake and translocation in two rice cultivars

Jianguo LIU,Hui CAI,Congcong MEI,Mingxin WANG

Journal Article

Enhanced activation of persulfate using mesoporous silica spheres augmented Cu–Al bimetallic oxide particles

Journal Article

Synthesis of ordered cerium-doped cubic mesoporous silica using long-chain ionic liquid as template

YUE Hongxia, ZHAO Hongmei, LIU Longjiang, WANG Siping, Ruan Qiong, WANG Tongwen

Journal Article

Computer modeling of crystal growth of silicon for solar cells

Lijun LIU, Xin LIU, Zaoyang LI, Koichi KAKIMOTO

Journal Article

The modification of titanium in mesoporous silica for Co-based Fischer–Tropsch catalysts

Journal Article

Copper nanoparticles/polyaniline-derived mesoporous carbon electrocatalysts for hydrazine oxidation

Tao Zhang, Tewodros Asefa

Journal Article